ENCYCLOPAEDIA HYDROCARBONS - OF - ENCICLOPEDIA ITALIANA - Treccani

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ENCYCLOPAEDIA HYDROCARBONS - OF - ENCICLOPEDIA ITALIANA - Treccani
ENCYCLOPAEDIA
     OF
HYDROCARBONS

           ISTITUTO DELLA
  ENCICLOPEDIA ITALIANA
    FONDATA DA GIOVANNI TRECCANI
©
         ALL RIGHTS RESERVED
              Copyright by
ISTITUTO DELLA ENCICLOPEDIA ITALIANA
 FONDATA DA GIOVANNI TRECCANI S.p.A.
                 2007

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ENCYCLOPAEDIA OF HYDROCARBONS

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ENCYCLOPAEDIA OF HYDROCARBONS

           volume iii

NEW DEVELOPMENTS:
ENERGY, TRANSPORT,
  SUSTAINABILITY
      SCIENTIFIC CO-ORDINATION
            Ugo Romano
INDEX OF VOLUME III

                           NEW DEVELOPMENTS:
                           ENERGY, TRANSPORT,
                             SUSTAINABILITY

                        1 – FROM PRIMARY SOURCES TO THE MARKET

Dante Casati, Raffaella Turatto
1.1 – EVOLVING TECHNOLOGIES AND POSSIBLE SCENARIOS                                          3
      1.1.1 – Scenarios and strategic decisions                                             3
      1.1.2 – Scenarios and reference markets                                               3
      1.1.3 – Factors for change and technological innovation                               4
      1.1.4 – The macroeconomic scenario                                                    5
      1.1.5 – Energy scenario                                                               5
      1.1.6 – Technological scenario                                                        6
      1.1.7 – The development scenario for the issue of ‘environment and sustainability’   15

        2 – HYDROCARBONS FROM NON-CONVENTIONAL AND ALTERNATIVE
                            FOSSIL RESOURCES

Maurice B. Dusseault
2.1 – OIL FROM NON-CONVENTIONAL SOURCES                                                    21
      2.1.1 – Non-conventional fossil fuels                                                21
      2.1.2 – Pressure-driven viscous oil technologies                                     25
      2.1.3 – Gravity drainage technologies                                                32
      2.1.4 – In situ combustion option                                                    39
      2.1.5 – Technology mixing and sequencing                                             41
      2.1.6 – Reservoir screening criteria                                                 44
      2.1.7 – Oil shales and mineable oil sands                                            45
      2.1.8 – Upgrading and transportation                                                 48
      2.1.9 – Environmental impact                                                         50
    2.1.10 – Predictions                                                                   52

Charles M. Boyer, Joseph H. Frantz, Creties D. Jenkins
2.2 – NON-CONVENTIONAL GAS                                                                 57
      2.2.1 – Introduction                                                                 57
      2.2.2 – Reservoir fundamentals                                                       60

                                                                                                XV
2.2.3 – Drilling, completion, and production                                72
       2.2.4 – Resources and reserves                                              74
       2.2.5 – Technology and future trends                                        75
       2.2.6 – Project summaries and comparisons of applied technologies           77
       2.2.7 – International potential for coalbed methane and shale gas           79
       2.2.8 – Conclusions                                                         80

  Gian Paolo Borghi
  2.3 – GAS HYDRATES                                                                85
        2.3.1 – Introduction                                                        85
        2.3.2 – The structure of hydrates                                           85
        2.3.3 – Hydrates as a problem in the oil industry                           91
        2.3.4 – Hydrates as a future energy resource                                98
        2.3.5 – Research and development activities in the gas hydrates sector     107

  Alberto Delbianco
  2.4 – HYDROCARBONS FROM THE DIRECT LIQUEFACTION OF SOLID FUELS                   113
        2.4.1 – Introduction                                                       113
        2.4.2 – Liquefaction technology                                            120
        2.4.3 – New-generation processes                                           126
        2.4.4 – Properties of coal liquids                                         128
        2.4.5 – Further developments of the technology                             129
        2.4.6 – Integration with hydrogen production technologies                  133
        2.4.7 – Process economics and development potential of the technology      134

  Alberto Delbianco, Romolo Montanari
  2.5 – EMERGING TECHNOLOGIES FOR THE CONVERSION OF RESIDUES                       137
        2.5.1 – Introduction                                                       137
        2.5.2 – Properties and chemical characteristics of non-conventional oils   139
        2.5.3 – Chemistry of the conversion and upgrading processes                143
        2.5.4 – Carbon rejection technologies                                      147
        2.5.5 – Hydrogen addition technologies: hydrocracking                      151
        2.5.6 – Technologies for the exploitation of oil shale                     156
        2.5.7 – Main development projects                                          158

  Giuseppe Bellussi, Roberto Zennaro
  2.6 – HYDROCARBONS FROM NATURAL GAS                                              161
        2.6.1 – Introduction                                                       161
        2.6.2 – Gas to Liquids process by means of the Fischer-Tropsch reaction    163
        2.6.3 – Products                                                           179

                                 3 – NEW UPSTREAM TECHNOLOGIES

  Ali Daneshy
  3.1 – UPSTREAM TECHNOLOGIES. NOVEL WELL AND PRODUCTION ARCHITECTURE              185
        3.1.1 – Introduction                                                       185
        3.1.2 – Horizontal drilling                                                186
        3.1.3 – Multilateral wells                                                 190

XVI
3.1.4 – Downhole flow regulators                                        196
     3.1.5 – Novel well architectures                                        198
     3.1.6 – Flow optimization                                               205

3.2 – ENHANCED OIL RECOVERY                                                  209
Emilio Causin
      3.2.1 – Processes                                                      209
Steven L. Bryant
      3.2.2 – Recovery factor optimization                                   214

Thomas Lockhart, Francesco Crescenzi
3.3 – SOUR OIL AND GAS MANAGEMENT                                            237
      3.3.1 – Introduction                                                   237
      3.3.2 – Origin of H2S in oil and gas accumulations                     238
      3.3.3 – H2S removal in small volume plants                             241
      3.3.4 – High volume sour gas treatment processes                       243
      3.3.5 – Sour gas re-injection                                          256
      3.3.6 – Sulphur storage and disposal                                   260
      3.3.7 – The sulphur market and new uses                                264

Francesca de Ferra
3.4 – BIOTECHNOLOGIES APPLIED TO OIL AND GAS EXPLORATION, PRODUCTION
      AND CONVERSION                                                         271
      3.4.1 – Microbiology associated with hydrocarbons                      271
      3.4.2 – Reactions                                                      274
      3.4.3 – Applications                                                   281
      3.4.4 – Biological activation of methane                               292

                                        4 – ENERGY CARRIERS

Mario Marchionna
4.1 – FROM SOURCES TO MARKET: ENERGY CARRIERS                                301
      4.1.1 – Introduction                                                   301
      4.1.2 – Life cycle of the energy carrier                               301
      4.1.3 – Conventional energy carriers                                   304
      4.1.4 – Innovative energy carriers                                     308
      4.1.5 – Conclusions                                                    315

Marco Nicola Carcassi
4.2 – THE HYDROGEN ECONOMY                                                   319
      4.2.1 – Introduction                                                   319
      4.2.2 – Characteristics of hydrogen                                    321
      4.2.3 – Production, transportation and storage of hydrogen             323
      4.2.4 – Advantages and disadvantages of hydrogen as an energy vector   325
      4.2.5 – Research and development programmes                            329
      4.2.6 – Conclusions                                                    333

                                                                              XVII
John R. Benemann, Paola Pedroni
   4.3 – BIOLOGICAL PRODUCTION OF H2: MECHANISMS AND PROCESSES      337
         4.3.1 – Introduction                                       337
         4.3.2 – Biological catalysts for H2 production             339
         4.3.3 – Bioreactors for H2 production                      341
         4.3.4 – Photobiological H2 production processes            344
         4.3.5 – Dark fermentations                                 350
         4.3.6 – Biohydrogen applications and potential             355

   Ernesto Scafè
   4.4 – TRANSPORT AND STORAGE OF HYDROGEN                          361
         4.4.1 – Introduction                                       361
         4.4.2 – Traditional transport and storage                  361
         4.4.3 – Innovative transport and storage                   364

                       5 – POWER GENERATION FROM FOSSIL RESOURCES

   Ennio Macchi, Giovanni Lozza, Stefano Consonni
   5.1 – LARGE-SCALE ELECTRICAL GENERATION SYSTEMS                  377
         5.1.1 – Introduction                                       377
         5.1.2 – Steam electric power stations                      384
         5.1.3 – Gas turbines                                       397
         5.1.4 – Combined cycles                                    404
         5.1.5 – Gasification and combined cycles (IGCC)            413

   Ennio Macchi, Giovanni Lozza
   5.2 – INDUSTRIAL COGENERATION                                    421
         5.2.1 – Introduction                                       421
         5.2.2 – Plants with external combustion prime movers       425
         5.2.3 – Plants with internal combustion prime movers       428

   Ennio Macchi, Stefano Campanari
   5.3 – DISTRIBUTED GENERATION                                     435
         5.3.1 – Introduction                                       435
         5.3.2 – Microgeneration technologies                       438
         5.3.3 – Trigeneration                                      457

   Ivano Miracca, Mario Molinari
   5.4 – POWER GENERATION WITH CARBON DIOXIDE SEGREGATION           461
         5.4.1 – Introduction                                       461
         5.4.2 – Technological development                          466
         5.4.3 – Future prospects                                   472

   Francesco Pittalis, Vincenzo Antonucci
   5.5 – FUEL CELLS FOR STATIONARY GENERATION                       475
         5.5.1 – Historical outlines                                475
         5.5.2 – Introduction                                       477

XVIII
5.5.3 – Fuels                                                    482
     5.5.4 – Low temperature fuel cells                               485
     5.5.5 – Medium and high temperature fuel cells                   491

Maurizio Cumo
5.6 – ADVANCED NUCLEAR SYSTEMS                                        499
      5.6.1 – Introduction                                            499
      5.6.2 – The six fourth-generation nuclear systems               501
      5.6.3 – High-temperature reactors                               505
      5.6.4 – Reduction in the radiotoxicity of waste                 508
      5.6.5 – The III+ generation reactors                            510

Giovanni Battista Zorzoli
5.7 – TRANSMISSION, DISTRIBUTION AND STORAGE OF ELECTRIC ENERGY       515
      5.7.1 – Introduction                                            515
      5.7.2 – Storage of electric energy                              515
      5.7.3 – The first steps                                         517
      5.7.4 – Types of transmission networks and connected problems   518
      5.7.5 – The North American network                              520
      5.7.6 – The European networks                                   522
      5.7.7 – Problems posed by deregulation                          524
      5.7.8 – Examination of a typical case of blackout               525
      5.7.9 – Distribution networks                                   527

                 6 – POWER GENERATION FROM RENEWABLE RESOURCES

6.1 – SOLAR ENERGY CONVERSION                                         531
Mauro Vignolini
      6.1.1 – Concentration systems                                   531
Francesca Ferrazza
      6.1.2 – Photovoltaic technology                                 547

Jacques Ruer
6.2 – WIND POWER GENERATION                                           561
      6.2.1 – The wind resource                                       561
      6.2.2 – Theory of wind turbines                                 563
      6.2.3 – Wind turbine regulation systems                         564
      6.2.4 – Turbine equipment                                       566
      6.2.5 – Typical characteristics of modern large turbines        570
      6.2.6 – Other types of wind turbines                            570
      6.2.7 – Development of onshore wind energy                      571
      6.2.8 – Development of offshore wind energy                     571

Wavegen
6.3 – WAVE AND TIDAL POWER GENERATION                                 575
      6.3.1 – Introduction                                            575
      6.3.2 – Historical perspective                                  579

                                                                        XIX
6.3.3 – Current status                                                          582
          6.3.4 – Estimation of wave energy resource and device performance               586
          6.3.5 – Environmental impact of wave and tidal devices                          590
          6.3.6 – Global prospects for the energy industry                                591

     Mario Fanelli, Piero Manetti, Mary Hana Dickson, Leonardo Zan
     6.4 – GEOTHERMAL ENERGY                                                              595
           6.4.1 – Introduction                                                           595
           6.4.2 – Nature of geothermal resources                                         597
           6.4.3 – Geothermal exploration                                                 603
           6.4.4 – Utilization of geothermal resources                                    604
           6.4.5 – Environmental impact                                                   609

     Vito Pignatelli, Andrea Robertiello
     6.5 – BIOMASS FOR RENEWABLE ENERGY                                                   611
           6.5.1 – Introduction                                                           611
           6.5.2 – The role of biomass in the energy spectrum                             613
           6.5.3 – Fuels from biomass                                                     615
           6.5.4 – Technologies for the use of biomass energy                             621
           6.5.5 – Conclusions                                                            628

                                       7 – ENERGY SYSTEMS ANALYSIS

     Alberto Tintinelli
     7.1 – LIFE CYCLE ASSESSMENT AND ENERGY SYSTEMS                                       633
           7.1.1 – Introduction                                                           633
           7.1.2 – Life cycle assessment method                                           634
           7.1.3 – Applications of life cycle assessment in the field of energy systems   641

     Teresa L. Hill, David H. Marks, Jefferson W. Tester
     7.2 – PATHWAYS TO A SUSTAINABLE ENERGY FUTURE                                        651
           7.2.1 – Introduction                                                           651
           7.2.2 – The future of fossil energy                                            652
           7.2.3 – Alternatives to fossil                                                 655
           7.2.4 – Energy systems                                                         664
           7.2.5 – Choosing options for a sustainable energy future                       666
           7.2.6 – Conclusions                                                            668

                                                    8 – TRANSPORT

     Alessandro Piccone, Giorgio Cornetti
     8.1 – RECIPROCATING INTERNAL COMBUSTION ENGINES                                      673
           8.1.1 – Introduction                                                           673
           8.1.2 – Architecture                                                           677
           8.1.3 – Combustion, emissions and control system                               684
           8.1.4 – Evolution                                                              695

XX
Jacopo D’Andria
8.2 – HYBRID DRIVE SYSTEMS                                                           699
      8.2.1 – Introduction                                                           699
      8.2.2 – Current environmental problems and potential solutions                 700
      8.2.3 – Hybrid-electric vehicles: historical outline and current situation     703
      8.2.4 – Features of the hybrid systems in use                                  704
      8.2.5 – Strengths and weaknesses of hybrid-electric vehicles
      8.2.6 – Possible developments in components for hybrid-electric vehicles
      8.2.7 – The future of the market for hybrid-electric vehicles

Fulvio Giavazzi, Patrizia Buttini, Carlo Perego
8.3 – POLLUTING EMISSIONS CAUSED BY TRANSPORT                                        717
      8.3.1 – Pollutants emitted by motor vehicles                                   717
      8.3.2 – Low-emission fuels                                                     729

Riccardo Maione, Luigi D’Elia
8.4 – LUBRICATION AND LUBRICANTS                                                     751
      8.4.1 – Introduction                                                           751
      8.4.2 – Functions and performance of lubricants for heavy-duty vehicles        757
      8.4.3 – Main components of lubricants for heavy-duty vehicles                  764
      8.4.4 – Lubricants for industry                                                768

                                           9 – SUSTAINABILITY

Andrea Robertiello, Alberto Tintinelli
9.1 – THE OIL INDUSTRY TOWARDS ZERO IMPACT                                           775
      9.1.1 – Introduction                                                           775
      9.1.2 – Oil cycle: upstream                                                    776
      9.1.3 – Oil cycle: downstream                                                  787
      9.1.4 – Natural gas cycle                                                      793
      9.1.5 – Operating instruments available for eliminating environmental impact   795

George J. Stosur
9.2 – SUSTAINABLE DEVELOPMENT IN THE OIL AND GAS INDUSTRY                            801
      9.2.1 – Defining sustainable development                                       801
      9.2.2 – The need for sustainable development                                   802
      9.2.3 – The precautionary principle                                            803
      9.2.4 – Industrial activities related to sustainable development               803
      9.2.5 – Greenhouse gases and global warming                                    807
      9.2.6 – Biodiversity and loss of habitat                                       808
      9.2.7 – The role of technology and research and development                    808
      9.2.8 – Regulatory processes at corporate, country and global level            809

Paul Freund
9.3 – CO2 CAPTURE AND STORAGE FROM FOSSIL FUELS                                      811
      9.3.1 – Introduction                                                           811
      9.3.2 – Sources of CO2                                                         812

                                                                                       XXI
9.3.3 – Methods of capturing CO2                                             814
        9.3.4 – Transportation of CO2                                                818
        9.3.5 – Storage of CO2                                                       819
        9.3.6 – Costs and benefits                                                   824
        9.3.7 – Environmental impact, risks, legal aspects and public acceptance     829
        9.3.8 – Monitoring, verification and commercial/regulatory requirements      832
        9.3.9 – Conclusions                                                          834

   John R. Benemann, Paola Pedroni
   9.4 – BIOFIXATION OF FOSSIL CO2 BY MICROALGAE FOR GREENHOUSE GAS ABATEMENT        837
         9.4.1 – Introduction                                                        837
         9.4.2 – Photosynthesis, microalgae productivity and GHG abatement           839
         9.4.3 – Microalgae cultivation systems and CO2 capture                      843
         9.4.4 – Microalgae harvesting and conversion to fuels                       847
         9.4.5 – Microalgae multipurpose processes for GHG abatement                 851
         9.4.6 – Economics and R&D issues                                            855
         9.4.7 – GHG abatement potential with microalgae processes                   857

   Abigail Entwistle, Timothy Reed, Paola Pedroni
   9.5 – BIODIVERSITY AND THE OIL AND GAS SECTOR                                     863
         9.5.1 – Introduction                                                        863
         9.5.2 – Biodiversity and the oil and gas sector                             866
         9.5.3 – Operationalizing biodiversity awareness in the oil and gas sector   870

   Ugo Romano, Franco Rivetti
   9.6 – CHEMICAL INDUSTRY AND SUSTAINABLE DEVELOPMENT                               879
         9.6.1 – Sustainability                                                      879
         9.6.2 – Sustainability in the chemical industry                             881
         9.6.3 – Innovation areas for sustainable chemistry                          887
         9.6.4 – Looking ahead                                                       907

                                 10 – ENVIRONMENTAL TECHNOLOGIES

   Ivo Allegrini
   10.1 – ATMOSPHERIC CHEMISTRY                                                      915
          10.1.1 – Introduction                                                      915
          10.1.2 – Atmospheric chemistry in the gas phase                            916
          10.1.3 – Atmospheric chemistry in the aqueous phase                        925
          10.1.4 – Depletion of stratospheric ozone                                  931

   Ivo Allegrini, Patrizia Buttini
   10.2 – EMISSION AND CONTROL OF GREENHOUSE GASES                                   937
          10.2.1 – Introduction                                                      937
          10.2.2 – Sources of greenhouse gas emissions                               945
          10.2.3 – Techniques for measuring greenhouse gases in ambient air          948
          10.2.4 – Techniques for measuring greenhouse gases in emissions            949
          10.2.5 – Strategies to control greenhouse gases                            950

XXII
Giovanni Grillo, Paola Pedroni
10.3 – POLLUTION PROCESSES IN SOIL AND WATER, MONITORING AND RISK ANALYSIS            955
       10.3.1 – Introduction                                                          955
       10.3.2 – Migration and transformation of hydrocarbons in the environment       955
       10.3.3 – Environmental characteristics of the principal groups of pollutants   959
       10.3.4 – Characterization and monitoring of pollution at a site                960
       10.3.5 – Modelling the movement of pollutants                                  964
       10.3.6 – Evaluation of the pollution at a site: risk assessment                966

                                                                                       XXIII
NOTES

UNITS OF MEASUREMENT

The units of measurement generally adopted are those of the Système International (SI), with corresponding mul-
tiples and submultiples. Only in particular contexts, typically connected with the petroleum industry, certain non-
SI units of current use have been maintained.

Main units of measurement adopted
ampere                         A     henry                             H    pascal                             Pa
angstrom                       Å     hertz                            Hz    poise                                P
atomic mass unit               u     horse-power                      hp    pound                               lb
bar                          bar     hour                               h   pounds per square inch            psi
barrel                       bbl     inch                         '' (in)   radian                            rad
becquerel                    Bq      joule                              J   second (angle)                       ⬙
British thermal unit        Btu      kelvin                            K    second (time)                        s
calorie                      cal     kilogram                         kg    siemens                              S
candela                       cd     kilowatt-hour                 kWh      sievert                            Sv
coulomb                        C     litre                              l
                                                                            standard cubic foot scf or SCF or sft3
darcy                          D     lumen                            lm
                                                                            steradian                           sr
day                            d     lux                               lx
                                                                            stock tank barrel                 stb
decibel                      dB      metre                             m
degree Celsius                °C     square metre                     m2    stokes                             St
degree Fahrenheit             °F     cubic metre                      m3    tesla                                T
degree (sexagesimal)            °    minute (angle)                     ⬘   tonne                                 t
electron volt                eV      minute (time)                   min    tonnes of oil equivalent          toe
farad                          F     mole                            mol    volt                                V
foot                       ' (ft)    newton                            N    watt                               W
gram                           g     nit                               nt   weber                             Wb
gray                         Gy      ohm                               Ω    yard                               yd
hectare                       ha     parts per million              ppm     year                               yr

TERMINOLOGY AND SPELLING

In the sectors of petroleum engineering and chemistry, of the petrochemical industry and of the earth sciences,
specific terms, acronyms and expressions are frequently used. The criterion adopted in this work is based on their
frequency of use, i.e. given two possible terms, the more common one has been used.
British spelling, according to the most authoritative reference works, has been adopted.

                                                                                                                 XXV
CHEMICAL NOMENCLATURE

  In the nomenclature of simple compounds, the rules of IUPAC (International Union of Pure and Applied Chemistry)
  have been adopted as far as possible, traditional names being limited to the cases admitted by IUPAC. When there
  are two or more names admitted, the commonest one is adopted.
  Two principal exceptions to the above rule have been applied in this work:
  • For organic compounds used in the petrochemical industry, the name adopted is that listed in: Wells G.M.
       (1999) Handbook of petrochemicals and processes, Aldershot, Ashgate; Brookfield (VT), Gower.
  • The British English spelling of sulphur and sulphur containing compounds is adopted.

  TRANSLITERATIONS

  In writing names belonging to other languages with an alphabet other than the Latin alphabet, the Romanization
  Tables compiled by the Library of Congress of Washington have been applied, introducing however certain modifications
  intended to reduce to a minimum the number of diacritical marks, and – in particular in the case of Arabic and Persian
  – adopting a number of transliterations by now accepted in local and international usage.

  Opposite page:
  The Val d’Agri deposits, along with those in the Sauro Valley, make up the largest energy resource ever discovered in Italy.
  In the picture a drill in the drilling stage. In the subsequent production stage the drill is no longer in sight: the wellhead is
  lodged in an underground space, substantially reducing its visual effect while guaranteeing utmost safety.
  Technological advances in the energy industry allow the possibility to minimize the environmental impact and respect
  biodiversity.

XXVI
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